Chemical and Environmental Engineering Group



























Hydrogen production by isothermal thermochemical cycles using La0.8Ca0.2MeO3ツアd (Me = Co, Ni, Fe and Cu) perovskites

Pテゥrez, A.; Orfila, M.; Linares, M.; Sanz, R.; Marugテ。n, J.; Molina, R.; Botas J.A.


Experimental evaluation and energy analysis of a two-step water splitting thermochemical cycle for solar hydrogen production based on La0.8Sr0.2CoO3-d perovskite

Orfila, M.; Linares, M.; Pテゥrez, A.; Barras-Garcテュa, I.; Sanz, R.; Marugテ。n, J.; Molina, R.; Botas, J.A.


Hydrogen production by thermochemical water splitting with La0.8Al0.2MeO3-d (Me= Fe, Co, Ni and Cu) perovskites prepared under controlled pH

Pテゥrez, A.; Orfila, M.; Linares, M.; Sanz, R.; Marugテ。n, J.; Molina, R.; Botas J.A.


Shifting pathways in the phenol/2-Propanol conversion over the tandem Raney Ni + ZSM-5 catalytic system

Garcテュa-Minguillテ。n, A. A.; Briones, L.; Serrano, D. P.; Botas, J. A.; Escola, J. M.


Hydrogen production by water splitting with Mn3-xCoxO4 mixed oxides thermochemical cycles: A thermodynamic analysis

Orfila, M.; Linares, M.; Molina, R.; Marugテ。n, J.; Botas, J. A.; Sanz, R.


Novel and versatile cobalt Azobenzene-Based Metal-Organic Framework as hydrogenツadsorbent

Montes-Andrテゥs, H.; Leo, P.; Orcajo, G.; Rodrテュguez-Diテゥguez, A.; Choquesillo-Lazarte, D.; Martos, C.; Botas, J. A.; Martテュnez, F., Calleja, G.


Experimental assessment of the cyclability of the Mn2O3/MnO thermochemical cycle for solar hydrogen production

Herradテウn, C.; Molina, R.; Marugテ。n, J.; Botas, J. A.


Thermochemical hydrogen production using manganese cobalt spinels as redox materials

Orfila, M.; Linares, M.; Molina, R.; Botas, J.A.; Marugテ。n, J.; Sanz, R.


Perovskite materials for hydrogen production by thermochemical water splitting

Orfila, M.; Linares, M.; Molina, R.; Botas, J. A.; Sanz, R.; Marugテ。n, J.


Hydrogen production by methane decomposition over pure silica SBA-15 materials

Gテウmez, G.; Botas, J. A.; Serrano, D. P.; Pizarro, P.


Hydrodeoxygenation of anisole as bio-oil model compound over supported Ni and Co catalysts: Effect of metal and support properties

Sankaranarayanan, T. M.; Berenguer, A.; Ochoa-Hernテ。ndez, C.; Moreno, I.; Jana, P.; Coronado, J.M.; Serrano, D.P.; Pizarro, P.


Hydrogen production through catalytic methane decomposition promoted by pure silica materials

Serrano, D. P.; Botas, J. A.; Pizarro, P.; Moreno, I.; Gテウmez, G.


Extrusion of Fe2O3/SBA-15 mesoporous material for application as heterogeneous Fenton-like catalyst

Pariente, M. I.; Martテュnez, F.; Botas, J. A.; Melero, J. A.


Intensified-Fenton process for the treatment of phenol aqueous solutions

Pariente, M. I.; Molina, R.; Melero, J. A.; Botas, J. A.; Martテュnez, F.


Study of the hydrogen production step of the Mn2O3/MnO thermochemical cycle

Marugテ。n, J.; Botas, J. A.; Molina, R.; Herradテウn, C.


Catalytic conversion of rapeseed oil for the production of raw chemicals, fuels and carbon nanotubes over Ni modified nanocrystalline and hierarchical ZSM5

Botas, J. A.; Serrano D. P.; Garcテュa A.; Ramos R.


Effect of ion-exchange modification on hydrogen and carbon dioxide adsorption behaviour of RhoZMOF material

Calleja, G.; Botas, J. A.; Martos, C.; Orcajo, G.; J. A. Villajos


Treatment of an agrochemical wastewater by integration of heterogeneous catalytic wet hydrogen peroxyde oxidation and rotating biological contactors

Pariente, M. I.; Siles, J. A.; Molina, R.; Botas, J. A.; Melero, J. A.; Martinez, F.


Kinetic and autocatalytic effects during the hydrogen production byツmethane decomposition over carbonaceous catalystsツ

Serrano, D. P.; Botas, J. A.; Pizarro, P.; Gテウmez, G.


Advances in the design of ordered mesoporous materials for the low-carbon catalytic hydrogen production

Serrano, D. P.; Coronado, J.; de la Peテアa O'shea, V.; Pizarro, P.; Botas, J. A.


Kinetic modeling of the first step of Mn2O3/MnO thermochemical cycle for solar hydrogen production

Botas, J. A.; Marugテ。n, J.; Molina, R.; Herradテウn, C.


Catalytic conversion of rapeseed oil into raw chemicals and fuels over Ni- and Mo-modified nanocrystalline ZSM-5 zeolite

Botas, J. A.; Serrano D. P.; Garcテュa A.; de Vicente, J.; Ramos R.


Influence of preoxidizing treatments on the preparation of iron-containing activated carbons for catalytic wet peroxide oxidation of phenol

Martテュnez, F.; Pariente, M. I.; Botas, J. A.; Melero, J. A.; Rubalcaba, A.


Study of the first step of the Mn2O3/MnO thermochemical cycle for solar hydrogen production

Marugテ。n, J.; Botas, J. A.; Martテュn, M.; Molina, R.; Herradテウn, C.


Comparison of metal and carbon catalysts for hydrogen production by methane decomposition

Guil-Lopez, R.; Botas, J. A.; Fierro, J. L. G.; Serrano, D. P.


Co8-MOF-5 as electrode for supercapacitors

Dテュaz, R.; Orcajo, M. G.; Botas, J. A.; Calleja, G.; Palma, J.


Effect of Zn/Co ratio in MOF-74 type materials containing exposed metal sites on their hydrogen adsorption behaviour and on their band gap energy

Botas, J. A.; Calleja, G.; Sテ。nchez-Sテ。nchez, M.; Orcajo, M. G.


Methane catalytic decomposition over ordered mesoporous carbons: A promising route for hydrogen production

Botas, J. A.; Serrano, D. P.; Guil-Lテウpez, R.; Pizarro, P.; Gテウmez, G.


On the Hydrogen adsorption over Zeolite-like MOF materials modified by ion exchange

Calleja, G.; Botas, J. A.; Sテ。nchez-Sテ。nchez, M.; Orcajo, M. G.

  • International Journal of Hydrogen Energy, 35, 99169923 (2010)

Cobalt doping of the MOF-5 framework and its effect on gas-adsorption properties

Botas, J. A.; Calleja, G.; Sテ。nchez-Sテ。nchez, M.; Orcajo, G.


Catalytic wet hydrogen peroxide oxidation of a petrochemical wastewater

Pariente, M. I.; Melero, J. A.; Martテュnez, F.; Botas, J. A.; Gallego, A. I.


Hydrogen production by methane decomposition: Origin of the catalytic activity of carbon materials

Serrano, D. P.; Botas, J. A.; Fierro, J. L. G.; Guil-Lテウpez, R.; Pizarro, P.; Gテウmez, G.


Oxidation of heavy 1- olefins (C12= - C20=) with TBHP using a modified Wacker system

Escola, J. M.; Botas, J. A.; Vargas, C.; Bravo, M.


Differences between the isostructural IRMOF-1 and MOCP-L porous adsorbents

Calleja, G.; Botas, J. A.; Orcajo, M. G.; Sテ。nchez-Sテ。nchez, M.


Assesment of Fe2O3/SiO2 catalysts for the continuous treatment of phenol aqueous solutions in a fixed bed reactor

Botas, J. A.; Melero, J. A.; Martテュnez, F.; Pariente, M. I.


Heterogeneous catalytic wet peroxide oxidation systems for the treatment of an industrial pharmaceutical wastewater

Melero, J. A.; Martテュnez, F.; Botas, J. A.; Molina, R.; Pariente, M. I.


H2 production from methane pyrolysis over commercial carbon catalysts: Kinetic and deactivation study

Serrano, D. P.; Botas, J. A.; Guil-Lopez, R.


Modified Wacker TBHP oxidation of 1-dodecene

Escola, J. M.; Botas, J. A.; Aguado, J.; Serrano, D. P.; Vargas, C.; Bravo, M.


Catalytic wet peroxide oxidation process for the continuous treatment of pulluted effluents on a pilot plant scale

Martテュnez, F.; Pariente, M. I.; Melero, J. A.; Botas, J. A.

  • Journal of Advanced Oxidation Technology, 11(1), 65-74 (2008)

Heterogeneous photo-Fenton oxidation of benzoic acid in water: Effect of operatin conditions, reaction by-products and coupling with biological treatment biological treatment

Pariente, M. I.; Martテュnez, F.; Melero, J. A.; Botas, J. A.; Velegraki, Th.; Xekoukoulotakis, N. P.; Mantzavinos, D.


Ordered mesoporous carbons as highly active catalysts for hydrogen production by CH4 decomposition

Serrano, D. P.; Botas, J. A.; Pizarro, P.; Guil-Lテウpez, R.; Gテウmez G.

  • Chemical Communications, 6585-6587 (2008)

Catalytic wet peroxidation of phenol in a fixed bed reactor

Martテュnez, F.; Pariente, M. I.; Melero, J. A.; Botas, J.A.; Gテウmez, E.

  • Water Science and Technology, 55(12), 75-81 (2007)

Characterization of adsorptive and hydrophobic properties of silicalite-1, ZSM-5, TS-1 and Beta zeolites by TPD techniques

Serrano, D. P.; Calleja, G.; Botas, J. A.; Gutiテゥrrez, F. J.

  • Separation and Purification Technology, 54 (1), 1-9 (2007)

Treatment of phenolic solutions by catalytic wet hydrogen peroxide oxidation over Fe2O3/SBA-15 extruded catalyst in a fixed bed reactor

Martテュnez, F.; Melero, J. A.; Botas, J. A.; Pariente, I.; Molina, R.

  • Industrial and Engineering Chemistry Research, 46, 4396-4405 (2007)

Nanocomposite Fe2O3/SBA-15: An efficient and stable catalyst for the catalytic wet peroxidation of phenolic aqueous solutions

Melero, J. A.; Calleja, G.; Martテュnez, F.; Molina, R.; Pariente M. I.


La economテュa del hidrテウgeno ツ una visiテウn global sobre la revoluciテウn energテゥtica del siglo XXI. 2. Aplicaciones convencionales del hidrテウgeno y pilas de combustible

San Miguel, G.; Dufour, J.; Calles, J. A.; Botas, J. A.

  • Acta Cientfica y Tecnolgica. Revista de la Asociacin Espaola de Cientficos, 10, 21-27. (2006)

Producciテウn limpia de hidrテウgeno a partir del gas natural

Calleja, G.; Serrano, D. P.; Botas, J. A.; Guil Lテウpez, R.

  • Energa & Empresa, Nコ 14, pp. 40 (2006)

La economテュa del hidrテウgeno ツ una visiテウn global sobre la revoluciテウn energテゥtica del siglo XXI. 1. Producciテウn y almacenamiento de hidrテウgeno

Botas, J. A.; Calles, J. A.; Dufour, J.; San Miguel, G.

  • Acta Cientfica y Tecnolgica. Revista de la Asociacin Espaola de Cientficos 9, 33-36 (2005)

Adsorciテウn de tolueno y agua en materiales mesoporosos MCM-41

Serrano, D. P; Calleja, G.; Botas, J. A.; Gutiテゥrrez, F. J.

  • XXIX Reunin Ib駻ica de Adsorcin, Oporto, Portugal. Sesin Oral (2004)

Adsorption and Hydrophobic Properties of Mesoestrutured MCM-41 and SBA-15 Materials for Volatile Organic Compound Removal

Serrano, D. P; Calleja, G.; Botas, J. A.; Gutiテゥrrez, F. J.

  • Industrial & Engineering Chemistry Research, 43, 7010-7018 (2004)

Estudio de las propiedades hidrofテウbicas de materiales tipo MCM-41 mediante ensayos de desorciテウn tテゥrmica programada

Serrano, D. P.; Calleja, G.; Botas, J. A.; Gutiテゥrrez, F. J.; Sevillano, S.

  • SECAT03, Torremolinos, M疝aga, Sesin Pster (2003)

Propiedades adsorbentes de materiales MCM-41 y zeolitas para la recuperaciテウn de COVs

Calleja, G.; Serrano, D.P.; Botas, J.A.; Gutiテゥrrez, F.J.

  • XXVII Reunin Ib駻ica de Adsorcin. Len (Espaa). (2002)

Adsorption properties of MCM-41 materials for the VOCs abatement

Calleja, G.; Serrano, D.P.; Botas, J.A.; Gutiテゥrrez, F.J.

  • Studies in Surface Science and Catalysis, 142, 1671-1678 (2002)

Temperature programmed desorption of isopentane and water on MCM-41 materials as a test for the VOCs abatement

Serrano, D. P.; Calleja, G.; Botas, J. A.; Gutiテゥrrez, F. J.

  • 9ー Congreso Mediterr疣eo de Ingeniera Qumica, Barcelona (Espaa). (2002)

Kinetic considerations of three-way catalysis in automobile exhaust converters

Botas, J.A.; Gutiテゥrrez Ortiz, M.A.; Gonzテ。lez Marcos, M.P.; Gonzテ。lez Marcos, J.A.; Gonzテ。lez Velasco, J.R.

  • Applied Catalysis B: Environmental, 32, 243-256 (2001)

TWC behaviour of platinum supported on high-surface and low-surface area cerium/zirconium mixed oxides

Gonzテ。lez Velasco, J.R.; Gutiテゥrrez Ortiz, M.A.; Marc, J.L.; Botas, J.A.; Gonzテ。lez Marcos, M.P.; Blanchard, G.

  • Topics in Catalysis, 16/17, 101-106 (2001)

N2O formation over CeO2-ZrO2 mixed oxides supported metal (Pt, Pd, Rh) catalysts for automotive exhaust control

Marc, J.L.; Gonzテ。lez Velasco, J.R.; Gutiテゥrrez Ortiz, M.A.; Botas, J.A.; Gonzテ。lez Marcos, M.P.; Blanchard, G.

  • Studies in Surface Science and Catalysis, 130, 1361-1366 (2000)

Effects of redox thermal treatments and feedstream composition on the activity of Ce/Zr mixed oxides for TWC applications

Gonzテ。lez Velasco, J.R.; Gutiテゥrrez Ortiz, M.A.; Marc, J.L.; Botas, J.A.; Gonzテ。lez Marcos, M.P.; Blanchard, G.

  • Applied Catalysis B: Environmental, 25, 19-29 (2000)

Catalytic activity study of ceria-zirconia mixed oxides submitted to different ageing treatments under simulated exhaust gases

Gonzテ。lez Velasco, J.R.; Gutiテゥrrez Ortiz, M.A.; Marc, J.L.; Botas, J.A.; Gonzテ。lez Marcos, M.P.; Blanchard, G.

  • Industrial & Engineering Chemistry Research, 39, 272-276 (2000)

Thermal aging of Pd/Pt/Rh automotive catalysts under cycled oxidizing-reducing environment

Gonzテ。lez Velasco, J.R.; Botas, J.A.; Ferret, R.; Gonzテ。lez Marcos, M.P.; Marc, J.L.; Gutiテゥrrez Ortiz, M.A.

  • Catalysis Today, 59, 395-402 (2000)

Durability of three-way platinum and rhodium catalysts in oxidising, reducing and cycled environments

Botas, J.A.; Ferret, R.; Gutiテゥrrez Ortiz, M.A.; Gonzテ。lez Velasco, J.R.

  • Journal de Chimie Physique, 12, 437-442 (1999)

Synthesis of cordierite monolithic honeycomb by solid state reaction of precursor oxides

Gonzテ。lez Velasco, J.R.; Gutiテゥrrez Ortiz, M.A.; Ferret, R.; Aranzabal, A.; Botas, J.A.

  • Journal of Materials Science, 34, 1999-2002 (1999)

Contribution of cerium/zirconium mixed oxides to the activity of a new generation of TWC

Gonzテ。lez Velasco, J.R.; Gutiテゥrrez Ortiz, M.A.; Marc, J.L.; Botas, J.A.; Gonzテ。lez Marcos M.P.; Blanchard, G.

  • Applied Catalysis B: Environmental, 22, 167-178 (1999)

HREM and XRD characterisation of thermal ageing of Pd/CeO2/Al2O3 automotive catalysts

Gonzテ。lez Velasco, J.R.; Gutiテゥrrez Ortiz, M.A.; Botas, J.A.; Bernal, S.; Gatica, J.M.; Pテゥrez Omil, J.A.

  • Studies in Surface Science and Catalysis, 126, 187-194 (1999)

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