Stereolithography 3D printed porous monolithic carbons for wastewater treatment by electrochemical technologies
Funding : Comunidad de Madrid (2022-T1/AMB-23946)
Start / End Years : 2023 - 2028
Principal Investigator : Díaz de Tuesta Triviño, José Luis
Research Team : - Díaz de Tuesta Triviño, José Luis - Martínez Castillejo, Fernando - Molina Gil, Raúl - Pariente Castilla, IsabelShow summary:
The aim of this project is the development of suitable photoresins and biobased photoresins for the 3Dprinted hypercrosslinked polymers with high yield to the carbonization to obtain carbon monolith with high performance in electrochemical technologies, mainly electroFenton, for the treatment of wastewater. The project deals with several topics: 1) the study of suitable photoresins to obtained 3D printed polymers; 2) the carbonization processes for the preparation of polymer-derived carbon monoliths; and 3) the development of wastewater techniques based in electrochemical technologies. The preparation of polymers will be carried out by radical polymerisation from photoresins based on different acrylate monomers, photoinitiators, dye, porogens and inhibitors. Then, the carbonization, activation and functionalization of the 3D printed polymers will be assessed to obtain active carbon monolith. Both polymers and carbon materials will be characterized using diverse analytical techniques. Finally, the active carbon monoliths will be applied in electrochemical treatments of wastewaters, mainly, electroFenton with the in-situ generation of hydrogen peroxide and high removal rates of organic pollutants.
Conversión de lodos de refinería en materiales conductores con aplicación en sistemas bioelectroquímicos sostenibles para el logro de aguas regeneradas
Funding : Ministerio de Ciencia e Innovación ()
Start / End Years : 2022 - 2025
URL : https://slud4matwater.cms.webnode.es/
Principal Investigator : Martínez Castillejo, Fernando y Molina Gil, Raúl
Research Team : - Cruz del Álamo, Ana - Díaz de Tuesta Triviño, José Luis - Martín Gamboa, Mario - Martínez Castillejo, Fernando - Molina Gil, Raúl - Pariente Castilla, Isabel - Puyol Santos, Daniel - Segovia González, Cintia - Segura Urraca, Yolanda
Magnetic CoFe2O4@carbon yolk-shell nanoparticles as catalysts for the catalytic wet peroxide oxidation of paracetamol: kinetic insights
Guari, N.M.C.; Silva, A.S.; Diaz de Tuesta, J.L.; Pottker, W.E.; Cordeiro, P.Y.; Gomes H.T.
- Global Nest Journal (in press) (2023)
- doi:10.30955/gnj.004309
Selective denitrification of simulated oily wastewater by oxidation using Janus-structured carbon nanotubes
Roman, Fernanda F.; Diaz de Tuesta, J.L.; Sanches, F.K.K.; Silva, A.S.; Marin, P.; Machado, B.; Serp, P.; Pedrosa, M.; Silva, A.M.T.; Faria, J.L; Gomes, H.T.
- Catalysis Today (in press) (2023)
- doi:10.1016/j.cattod.2023.01.008
17 a-Ethinylestradiol Degradation in Continuous Process by Photocatalysis Using Ag/Nb2O5 Immobilized in Biopolymer as Catalyst
Lenzi, G.G.; Abreu, E.; Fuziki, M.E.K.; Fidelis, M.Z.; Brackmann, R.; Diaz de Tuesta, J.L.; Gomes, H.T.; dos Santos, O.A.A.
- Topics in Catalysis, 65(13-16), 1225 - 1234 (2022)
- doi:10.1007/s11244-022-01624-3
Performance and modeling of Ni(II) adsorption from low concentrated wastewater on carbon microspheres prepared from tangerine peels by FeCl3-assisted hydrothermal carbonization
Diaz De Tuesta, J. L.; Roman, F.F.; Marques, V.C.; Silva, A.S.; Silva, A.P.F.; Bosco, T.; Shinibekova, A.A.; Aknur, S.; Kalmakhanova, M.S.; Massalimova, B.K.; Arrobas, M.; Silva, A.M.T.
- Journal of Environmental Chemical Engineering, 10 (5), 108143 (2022)
- doi:10.1016/j.jece.2022.108143
A systematic literature review on the conversion of plastic wastes into valuable 2D graphene-based materials
Vieira, O.; Ribeiro, R.S.; Diaz de Tuesta, J.L.; Gomes, H.T.; Silva, A.M.T.
- Chemical Engineering Journal, 428, 131399 (2022)
- doi:10.1016/j.cej.2021.131399
Synthesis of low-density polyethylene derived carbon nanotubes for activation of persulfate and degradation of water organic micropollutants in continuous mode
Ribeiro, R.S.; Octávia Vieira, R.F.; Roman, F.F.; Diaz de Tuesta, J.L.; Silva, A.M.T.; Gomes, H.T.
- Journal of Environmental Management, 308, 114622 (2022)
- doi:10.1016/j.jenvman.2022.114622
Assessment of Pretreatments for Highly Concentrated Leachate Waters to Enhance the Performance of Catalytic Wet Peroxide Oxidation with Sustainable Low-Cost Catalysts
de Freitas Batista, G.; Roman, F.F.; Diaz de Tuesta, J.L.; Vieira Mambrini, R.; Praça, P.; Gomes, H.T.
- Catalysts, 12, 238 (2022)
- doi:10.3390/catal12020238
3D-printed activated carbon for post-combustion CO2 capture
Zafanelli, Lucas F.A.S.; Henrique, A.; Steldinger, H.; Diaz de Tuesta, J.L.; Gläsel, J.; Rodrigues, A.E.; Gomes, H.T.; Etzold, B.J.M.; Silva, J.A.C.
- Microporous and Mesoporous Materials, 335, 111818 (2022)
- doi:10.1016/j.micromeso.2022.111818
Doxorubicin delivery performance of superparamagnetic carbon multi-core shell nanoparticles: pH dependence, stability and kinetic insight
Santos Silva, A.; Diaz de Tuesta, J.L.; Sayuri Berberich, T.; Delezuk Inglez, S.; Bertão, A.R.; Çaha, I.; Leonard Deepak, F.; Bañobre-López, M.; Gomes, H.T.
- Nanoscale (in press) (2022)
- doi:10.1039/d1nr08550f
Application of adsorbent materials to remove heavy metals in leachate from a municipal landfill treatment plant
Cardoso, J.S.; Fernández-Delgado, M.; Vertonha, M.T.; Cabral, D.; Silva, A.S.; Roman, F.F.; Díaz de Tuesta, J.L.; Arrobas, M.; Coca, M.; Brito, P.; Gomes, H.T.
- Progress in Industrial Ecology, 15(2-4), 111 - 127 (2022)
- doi:10.1504/PIE.2022.125612
Hydrochars from compost derived from municipal solid waste: Production process optimization and catalytic applications
Roman, F.F.; Diaz de Tuesta, J.L.; Praça, P.; Silva, A.M.T.; Faria, J.L.; Gomes, H.T.
- Journal of Environmental Chemical Engineering, 9, 104888 (2021)
- doi:10.1016/j.jece.2020.104888
Degradation of emerging contaminants: Effect of thermal treatment on Nb2O5 as photocatalyst
Abreu, E.; Fidelis, M.Z.; Fuziki, M.E.; Malikoski, R.M.; Mastsubara, M.C.; Imada, R.E.; Diaz de Tuesta, J.L.; Gomes, H.T.; Anziliero, M.D.; Baldykowski, B.; Dias, D.T.; Lenzi, G.G.
- Journal of Photochemistry & Photobiology, A: Chemistry, 419, 113484 (2021)
- doi:10.1016/j.jphotochem.2021.113484
Kinetic insights on wet peroxide oxidation of caffeine using EDTA-functionalized low-cost catalysts prepared from compost generated in municipal solid waste treatment facilities
Diaz de Tuesta, J.L.; de Almeida, F.V.M. ; Oliveira, J.R.P. ; Praça, P.; Guerreiro, M.C.; Gomes, H.T.
- Environmental Technology & Innovation, 24, 101984 (2021)
- doi:10.1016/j.eti.2021.101984
Assisted hydrothermal carbonization of agroindustrial byproducts as effective step in the production of activated carbon catalysts for wet peroxide oxidation of micro-pollutants
Diaz de Tuesta, J.L.; Saviotti, M.C.; Roman, F.F.; Pantuzza, G.F.; Sartori, H.J.F.; Shinibekova, A.; Kalmakhanova, M.S.; Massalimova, B.K.; Pietrobelli, J.M.T.A.; Lenzi, G.G.; Arrobas, M.; Gomes, H.T.
- Journal of environmental chemical engineering, 9, 105004 (2021)
- doi:10.1016/j.jece.2020.105004
New insights on the removal of diclofenac and ibuprofen by CWPO using a magnetite-based catalyst in an up-flow fixed-bed reactor
Huacallo-Aguilar, Y.; Diaz de Tuesta, J.L.; Álvarez-Torrellas, S.; Gomes, H.T.; Larriba, M.; Ovejero, G.; García, J.
- Journal of Environmental Management, 281, 111913 (2021)
- doi:10.1016/j.jenvman.2020.111913
Carbon-Based Materials for Oxidative Desulfurization and Denitrogenation of Fuels: A Review
Roman, F.F.; Díaz de Tuesta, J.L.; Silva, A.M.T., Faria, J.L.; Gomes, H.T.
- Catalysts, 11, 1239 (2021)
- doi:10.3390/catal11101239
Pillared clays from natural resources as catalysts for catalytic wet peroxide oxidation: Characterization and kinetic insights
Seitovna Kalmakhanova, M.; Diaz de Tuesta, J.L.; Kabykenovna Massalimova, B.; Gomes, H.T.
- Environ. Eng. Res., 25, 2, 186-196 (2020)
- doi:10.4491/eer.2018.402
The pH effect on the kinetics of 4-nitrophenol removal by CWPO with doped carbon black catalysts
Diaz de Tuesta, J.L.; Quintanilla, A.; Casas, J.A.; Morales-Torres, S.; Faria, J.L.; Silva, A.M.T.; Gomes, H.T.
- Catalysis Today 356, 216225 (2020)
- doi:10.1016/j.cattod.2019.08.033
Compost from Municipal Solid Wastes as a Source of Biochar for CO2 Capture
Karimi, M.; Diaz de Tuesta, J.L.; Gonçalves, C.N.d.P.; Gomes, H.T.; Rodrigues, A.E.; Silva, J.A.C.
- Chem. Eng. Technol. 43, 7, 13361349 (2020)
- doi:10.1002/ceat.201900108
Catalysts Prepared with Matured Compost Derived from Mechanical-Biological Treatment Plants for the Wet Peroxide Oxidation of Pollutants with Different Lipophilicity
Diaz de Tuesta, J.L.; Pantuzza, G.F.; Silva, A.M.T.; Praça, P.; Faria, J.L.; Gomes, H.T.
- Catalysts 10, 1243 (2020)
- doi:10.3390/catal10111243
Janus amphiphilic carbon nanotubes as Pickering interfacial catalysts for the treatment of oily wastewater by selective oxidation with hydrogen peroxide
Diaz de Tuesta, J.L.; Machado, B.F.; Serp, P.; Silva, A.M.T.; Faria, J.L.; Gomes, H.T.
- Catalysis Today, 356, 205-215 (2020)
- doi:10.1016/j.cattod.2019.07.012
Simulation and Optimization of the CWPO Process by Combination of Aspen Plus and 6-Factor Doehlert Matrix: Towards Autothermal Operation
Diaz de Tuesta, J.L.; Quintanilla, A.; Moreno, D.; Ferro, V.R.; Casas, J.A.
- Catalysts 10, 548 (2020)
- doi:10.3390/catal10050548
Adsorption of Sudan-IV contained in oily wastewater on lipophilic activated carbons: kinetic and isotherm modelling
Diaz de Tuesta, J.L.; Silva, A.M.T.; Faria, J.L.; Gomes, H.T.
- Environmental Science and Pollution Research 27, 2077020785 (2020)
- doi:10.1007/s11356-020-08473-1
Condensation By-Products in Wet Peroxide Oxidation: Fouling or Catalytic Promotion? Part I. Evidences of an Autocatalytic Process
Quintanilla, A.; Diaz de Tuesta, J.L.; Figueruelo, C.; Munoz, M.; Casas J.A.
- Catalysts 9, 516 (2019)
- doi:10.3390/catal9060516
Condensation By-Products in Wet Peroxide Oxidation: Fouling or Catalytic Promotion? Part II: Activity, Nature and Stability
Quintanilla, A.; Diaz de Tuesta, J.L.; Figueruelo, C.; Munoz, M.; Casas J.A.
- Catalysts 9, 518 (2019)
- doi:10.3390/catal9060518
Wet Peroxide Oxidation of Paracetamol Using Acid Activated and Fe/Co-Pillared Clay Catalysts Prepared from Natural Clays
Santos Silva, A.; Seitovna Kalmakhanova, M.; Kabykenovna Massalimova, B.; Diaz de Tuesta, J.L.; Gomes, H.T.
- Catalysts 9, 705 (2019)
- doi:10.3390/catal9090705
Removal of Sudan IV from a simulated biphasic oily wastewater by using lipophilic carbon adsorbents
Diaz de Tuesta, J.L.; Silva, A.M.T.; Faria, J.L.; Gomes, H.T.
- Chemical Engineering Journal, 347, 963971 (2018)
- doi:10.1016/j.cej.2018.04.105
CO2 Capture in Chemically and Thermally Modified Activated Carbons Using Breakthrough Measurements: Experimental and Modeling Study
Karimi, M.; Silva, J.A.C.; Gonc¸alves, C.N.d.P.; Diaz de Tuesta, J.L.; Rodrigues, A.E.; Gomes, H.T.
- Ind. Eng. Chem. Res., 57, 11154-11166 (2018)
- doi:10.1021/acs.iecr.8b00953
Kinetic modeling of wet peroxide oxidation with a carbon black catalyst
Diaz de Tuesta, J.L.; Quintanilla, A.; Casas, J.A.; Rodriguez, J.J.
- Applied Catalysis B: Environmental, 209, 701710 (2017)
- doi:10.1016/j.apcatb.2017.03.031
P-, B- and N-doped carbon black for the catalytic wet peroxide oxidation of phenol: Activity, stability and kinetic studies
Diaz de Tuesta, J.L.; Quintanilla, A.; Casas, J.A.; Rodriguez, J.J.
- Catalysis Communications, 102, 131135 (2017)
- doi:10.1016/j.catcom.2017.09.012
Application of high-temperature Fenton oxidation for the treatment of sulfonation plant wastewater
Díaz de Tuesta, J.L.; García-Figueruelo, C.; Quintanilla, A.; Casas, J.A.; Rodriguez, J.J.
- J Chem Technol Biotechnol, 90, 18391846 (2015)
- doi:10.1002/jctb.4494
Synthesis and characterization of low molecular weight poly(1-butene) macromolecules prepared using metallocene catalysts
Diez de Tuesta, J. L.; Casas, E.; Moreno, J.; Perez Nebreda, P.; Escola, J. M.; Van Grieken, R.
- Applied Catalysis A: General, 460-461, 70-77 (2013)
- doi:10.1016/j.apcata.2013.04.020
Conversion of polyethylene into transportation fuels by the combination of thermal cracking and catalytic hydroreforming over Ni-Supported hierarchical Beta zeolite
Escola, J. M.; Aguado, J.; Serrano, D. P.; Briones, L.; Díaz de Tuesta, J. L.; Calvo, R.; Fernandez, E.
- Energy&Fuels, 26, 3187-3195 (2012)
- doi:10.1021/ef300938r